SOLVED: The diagram illustrates the mechanism of the pyruvate dehydrogenase complex. As the species labeled "Reduced lipoyllysine" oxidizes, the released electrons are transferred to CoA-SH. Pyruvate is then converted to acetyl CoA, which is further reduced to acetyl dihydrolipoamide. The reduced dihydrolipoamide is then oxidized by dihydrolipoamide dehydrogenase, transferring the electrons to FAD and NAD .
SOLVED: The diagram illustrates the mechanism of the pyruvate de…
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In the first bypass step of gluconeogenesis, the conversion of pyruvate to phosphoenolpyruvate (PEP), pyruvate is carboxylated by pyruvate carboxylase to oxaloacetate, which is subsequently decarboxylated to PEP by PEP carboxykinase (Chapter 14 ). Because the addition of CO2 is directly followed by the loss of CO2, you might expect that in tracer experiments, the ^14 C of ^14 CO2 would not be incorporated into PEP, glucose, or any intermediates in gluconeogenesis. However, investigators find tha
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