Carbonate ester - Wikipedia
In organic chemistry, a carbonate ester (organic carbonate or organocarbonate) is an ester of carbonic acid. This functional group consists of a carbonyl group flanked by two alkoxy groups.
Bicarbonate and Alkyl Carbonate Radicals: Structural Integrity and ...
We now report experimental studies for a model of bicarbonate radical, namely, methyl carbonate (methoxycarbonyloxyl) radical, complemented by DFT computations at the CAM-B3LYP level …
Common alkyl carbonates used in commercial electrolytes. Linear alkyl ...
Linear alkyl carbonates (diethylcarbonate, DEC, and dimethylcarbonate, DMC) and cyclic alkyl carbonates (propylene carbonate, PC, and ethylene carbonate, EC). DEC and DMC structures,...
Carbonate synthesis - Organic Chemistry Portal
A photo-on-demand in situ synthesis of chloroformates of primary alkyl alcohols in the presence of CHCl 3 and oxygen followed by addition of alcohols or amines enables a one-pot synthesis of …
Characterization of Lithium Alkyl Carbonates by X-ray …
Aug 2, 2005 · Lithium alkyl carbonates ROCO 2 Li result from the reductive decomposition of dialkyl carbonates, which are the organic solvents used in the electrolytes of common lithium …
Alkyl-Carbonates | Combustion
Alkyl-Carbonates. Dimethyl Carbonate; Organophosphorus Compounds; Effect of NO addition to Hydrocarbons; 2,4,6-Tri-NitroToluene (TNT)
Improving Linear Alkyl Carbonate Electrolytes with Electrolyte ...
Apr 14, 2017 · The results showed that cells with linear alkyl carbonate electrolytes outperformed cells with EC-based electrolytes having state-of-the-art additive blends and cells with …
Trends in Na-Ion Solvation with Alkyl-Carbonate Electrolytes for …
Sep 15, 2015 · Based on the highest binding energy (ΔE b), enthalpy of solvation (ΔH (sol)), and Gibbs free energy of solvation (ΔG (sol)) values for the interaction of Na + ion with carbonate …
Degradation mechanism of alkyl carbonate solvents used in …
Oct 1, 1997 · The degradation mechanism of electrolytes in the lithium-ion cell with LiCoO 2 and graphite electrodes was investigated by analyzing: (i) the composition of generated gases; (ii) …
Weakly solvated EC-free linear alkyl carbonate electrolytes for Ni …
Dec 22, 2022 · Here, in this work, we propose an EC-free low-cost linear alkyl carbonate-based electrolyte and realize the high-voltage application in rechargeable lithium battery.